Spectroscopic Studies of Charge Transfer Complexes. XIV. Ethyl Isothiocyanate and Allyl Isothiocyanate with Iodine.
نویسندگان
چکیده
منابع مشابه
Spectroscopic Study of Charge Transfer Complexes of Dibenzo-24-crown-8 (DB24C8) with Iodine in Three Chlorinated Solvents
Charge Transfer (CT) complexes formed between dibenzo-24-crown-8 (DB24C8) as an electron donor with the σ-electron acceptor iodine (I2) in chloroform, dichloromethane, and 1,2-dichloroethane solutions have been studied by different spectroscopic techniques at room temperature. The spectral studies of the complexes were det...
متن کاملAllyl isothiocyanate as a cancer chemopreventive phytochemical.
Allyl isothiocyanate (AITC), which occurs in many common cruciferous vegetables, is widely and often frequently consumed by humans. Besides antimicrobial activity against a wide spectrum of pathogens, it showed anticancer activity in both cultured cancer cells and animal models, although the underlining mechanisms remain largely undefined. Bioavailability of AITC is extremely high, as nearly 90...
متن کاملNear-silence of isothiocyanate carbon in (13)C NMR spectra: a case study of allyl isothiocyanate.
(1)H and (13)C NMR spectra of allyl isothiocyanate (AITC) were measured, and the exchange dynamics were studied to explain the near-silence of the ITC carbon in (13)C NMR spectra. The dihedral angles α = ∠(C1-C2-C3-N4) and β = ∠(C2-C3-N4-C5) describe the conformational dynamics (conformation change), and the bond angles γ = ∠(C3-N4-C5) and ε = ∠(N4-C5-S6) dominate the molecular dynamics (confor...
متن کاملNear-Silence of Isothiocyanate Carbon in C NMR Spectra: A Case Study of Allyl Isothiocyanate
H and C NMR spectra of allyl isothiocyanate (AITC) were measured, and the exchange dynamics were studied to explain the near-silence of the ITC carbon in C NMR spectra. The dihedral angles α = ∠(C1−C2−C3−N4) and β = ∠(C2−C3−N4−C5) describe the conformational dynamics (conformation change), and the bond angles γ = ∠(C3−N4−C5) and ε = ∠(N4−C5−S6) dominate the molecular dynamics (conformer flexibi...
متن کاملTRPA1 agonists--allyl isothiocyanate and cinnamaldehyde--induce adrenaline secretion.
Thermosensitive transient receptor potential (TRP) channels, especially TRPV1 and TRPA1, are activated by the pungent compounds present in spices. TRPV1 activation by the intake of capsaicin, the irritant in hot pepper, induces adrenaline secretion and increases energy consumption. TRPV1 is mainly expressed in the sensory neurons and coexpressed with TRPA1 at a high frequency. However, the mech...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1965
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.19-1897